Product ID:BRAKE FLUID DOT 3 12OZ VALV PROF CHEM BF-12
MSDS Date:02/10/1995
FSC:6850
NIIN:00N092113
Status Code:A
MSDS Number: CJQHB

ASHLAND CHEMICAL CO

COLUMBUS, OH 43216
US

Emergency Phone: 800-274-5263

Info Phone: 614-790-3333

Cage: 34897

ASHLAND CHEMICAL CO

2219 COLUMBUS, OH 43216-2219 US

Telephone: 614-790-3333/800-274-5263

Cage: 34897

TRIETHYLENE GLYCOL MONOBUTYL ETHER

CAS: 143-22-6

RTECS: KJ9450000

DIETHYLENE GLYCOL MONOBUTYL ETHER

CAS: 112-34-5

RTECS: KJ9100000

DIETHYLENE GLYCOL

CAS: 111-46-6

RTECS: ID5950000

DIETHYLENE GLYCOL MONOPROPYL ETHER

CAS: 6881-94-3

DIETHYLENE GLYCOL MONOETHYL ETHER

CAS: 111-90-0

RTECS: KK8750000

TRIETHYLENE GLYCOL MONOETHYL ETHER

CAS: 112-50-5

RTECS: KK8950000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: CAN CAUSE IRRITATION.
SYMPTOMS INCL STINGING, TEARING, REDNESS, AND SWELLING OF EYES.
SKIN: MAY CAUSE MILD IRRITATION. PROLONGED OR REPEATED CONTACT MAY
DRY SKIN. SYMPTOMS MAY INCL REDNESS , BURNING, DRYING AND CRACKING
OF SKIN, AND SKIN BURNS. INGEST: SWALLOWING SMALL AMOUNTS OF THIS
MATERIAL DURING NORMAL HANDLING IS NOT LIKELY TO CAUSE HARMFUL
EFFECTS. SWALLOWING LARGE AMOUNTS MAY BE HARMFUL. INHAL: IT IS
POSSIBLE TO BREATHE THIS MATERIAL UNDER CERTAIN CONDITIONS OF
HANDLING AND USE (FOR EXAMPLE, DURING HEATING, SPRAYING, OR
STIRRING). SYMPTOMS OF EXPOSURE: (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZS: MOUTH AND THROAT IRRITATION
(SORENESS, DRY OR SCRATCHY FEELING, COUGH), STOMACH OR INTESTINAL
UPSET (NAUSEA, VOMITING, DIARRHEA), IRRITATION (NOSE, THROAT,
AIRWAYS), CENTRAL NERVOUS SYSTEM DEPRESSION (DIZZINESS,
DROWSINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS),
KIDNEY DAMAGE, LIVER DAMAGE. TARGET ORGAN EFFECTS: NO DATA.

First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE OXYG/ARTF
RESP) . EYES: IF SYMPS DEVELOP, MOVE TO FRESH AIR. FLUSH GENTLY
W/WATER WHILE HOLDING EYELIDS APART FOR AT LST 15 MINS. IF SYMPS
PERSIS T/THERE IS ANY VISUAL DFCLTY, SEEK MED ATTN. SKIN: REMOVE
CONTAMD CLTHG. WASH EXPOSED AREA W/SOAP & WATER. IF SYMPS PERSIST,
SEEK MED ATTN. LAUNDER CLTHG BEFORE REUSE. INGEST: SEEK MED ATTN.
IF INDIVI DUAL IS DROWSY/UNCON, DO NOT GIVE ANYTHING BY MOUTH;
PLACE INDIVIDUAL ON LEFT SIDE W/HEAD DOWN. CONT PHYS, MED
FACILITY/POIS CTL CTR FOR ADVICE ABOUT WHETHER TO INDUCE VOMIT.
(SUDPAT)

Flash Point Method:COC
Flash Point:=121.1C, 250.F
Extinguishing Media:ALCOHOL FOAM, WATER FOG, CARBON DIOXIDE, DRY
CHEMICAL.
Fire Fighting Procedures:WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE
VIOLENT & POSSIBLY ENDANGER LIFE OF FIREFIGHTER. WEAR A NIOSH
APPRVD SCBA W/FULL FACEPIECE OPERATED IN POSITIVE PRESS DEMAND MODE
W/APPROP TURN-OUT GEAR & CH EM RESIST PERSONAL PROT EQUIP. REFER TO
PERSONAL PROT EQUIP SECTION OF THIS MSDS.
Unusual Fire/Explosion Hazard:NEVER USE WELDING OR CUTTING TORCH ON OR
NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN
IGNITE EXPLOSIVELY.

Spill Release Procedures:SM SPILL: ABSORB LIQ ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LG SPILL: PVNT RUN-OFF TO SEWERS,
STREAMS/OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY PROPER
AUTH AS REQD, THAT SPILL HAS OCCU RED. PERSONS NOT WEARING PROT
EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN
COMPLETED. STOP SPILL @ SOURCE, DIKE AREA OF SPILL TO PVNT
SPREADING, PUMP LIQ TO SALVAGE (SUPDAT)

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED.
Other Precautions:SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES
(VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THE
DATA SHEET MUST BE OBSERVED.

Respiratory Protection:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR NORMAL WORK CLOTHING COVERING ARMS AND LEGS.
Supplemental Safety and Health
FIRST AID PROC: IF POSSIBLE, DO NOT LEAVE INDIVIDUAL UNATTENDED. SPILL
PROC: TANK. REMAINING LIQ MAY BE TAKEN UP ON SAND, CLAY, EARTH,
FLOOR ABSORB/OTHER ABSORB MATL & SHOVELED INTO CNTNRS.

Boiling Pt:=205.C, 401.F
Spec Gravity:1.03 @ 77.00F
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:CLEAR & COLORLESS LIQUID HOMOGENEOUS SOLUTION.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:MAY FORM: CARBON DIOXIDE AND CARBON
MONOXIDE, VARIOUS HYDROCARBONS.

Waste Disposal Methods:DESTROY BY LIQUID INCINERATION. DISPOSE OF IN
ACCORDING WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.

Toxicological Information:NO DATA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA.

Transport Information:DOT INFORMATION - 49 CFR 172.101. DOT
DESCRIPTION: NOT REGULATED. CONTAINER/MODE: CASES/SURFACE - NO
EXCEPTIONS. NOS COMPONENT: NONE. RQ (REPORTABLE QUANTITY) - 49 CFR
172.101: NOT APPLICABLE.

SARA Title III Information:SARA 302 COMPONENTS - 40 CFR 355 APPENDIX A:
NONE. SECTION 311/312 HAZARD CLASS - 40 CFR 370.2: IMMEDIATE,
DELAYED. SARA 313 COMPONENTS - 40 CFR 372.65. SECTION 313
COMPONENT(S): TRIETHYLENE GLYCOL MO NOBUTYL ETHER, CAS # 143-22-6.
INTERNATIONAL REGULATIONS-INVENTORY STATUS-NOT DETERMINED.
Federal Regulatory Information:US FEDERAL REGULATIONS. TSCA (TOXIC
SUBSTANCES CONTROL ACT) STATUS. TSCA (UNITED STATES) THE
INTENTIONAL INGREDIENTS OF THIS PROD ARE LISTED. CERCLA RQ - 40 CFR
302.4: NONE.
State Regulatory Information:STATE AND LOCAL REGULATIONS. CALIFORNIA
PROPOSITION 65: NONE. PENNSYLVANIA, RTK LABEL INFORMATION: ETHANOL,
2,2'-OXYBIS- CAS # 111-46-6.